Reagents and Reaction Mechanism Questions and Answer for CSIR NET, GATE, IIT JAM
Welcome to your Chemarticle in a new article on the reaction and reagent question-answer series for a beginner to advance level Examination aspirant. We talked about the conceptual question and answer series for CSIR NET GATE IIT JAM and other entrance examinations like DRDO, NTPC, BHU, DU, NIPER, etc. This session starts on the Reagent -Chemclip.com website you can follow the link given below.
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| Reagents -Reaction mechanism chemistry A to Z: Complet syllabus. |
Preparation of Reagents and Reaction Chemistry
The reagent and their reaction mechanism are important in organic chemistry for any national-level examination aspect. First of all, we have to release the session for learning from beginner to Advanced. We hope that it is helpful for your exam preparation. Reagents and Reaction mechanism Topic-wise discussion.
| Organic Reagents | Topic | Link |
|---|---|---|
| Alkylation Using LDA Reagents - Carruthers book for modern organic synthesis - Carbon-Carbon signal bond formation with reaction mechanism. | CLICK HERE | |
| Organic Reagents and Reagent Question-2 solution | Alkylation ketone Using KOH, Bu4NBr, and MeI Reagents - Carruthers book for modern organic synthesis - Carbon-Carbon signal bond formation with reaction mechanism. | CLICK HERE |
| Organic Reagents and Reagent Question-3 solution | Alkylation ketone Using LDA, THF, and benzyl halide Reagents - Carruthers book for modern organic synthesis - Carbon-Carbon signal bond formation with reaction mechanism. | CLICK HERE |
| Organic Reagents and Reagent Question-4 solution | Alkylation ketone Using t-BuOK, t-BuOH, and MeI Reagents - Carruthers book for modern organic synthesis - Carbon-Carbon signal bond formation with reaction mechanism. | CLICK HERE |
| Organic Reagents and Reagent Question-5 solution | Alkylation ketone Using t-BuOK, t-BuOH, and MeI Reagents and protection using: (i) Na-OEt, EtOH, HCO2Et (ii) BuSH, TsOH deprotection: KOH, H2O, ethylene glycol, reflux - Carruthers book for modern organic synthesis - Carbon-Carbon signal bond formation with reaction mechanism. |
CLICK HERE |
| Organic Reagents and Reagent Question-6 solution | Reagent KNH2 liquid ammonia| Reaction Mechanism - Carruthers book for modern organic synthesis - Carbon-Carbon signal bond formation with reaction mechanism. |
CLICK HERE |
| Organic Reagents and Reagent Question-7 solution | Reagents NaH, BuLi, and Alkyl bromide| Reaction Mechanism - Carruthers book for modern organic synthesis - Carbon-Carbon signal bond formation with reaction mechanism. |
CLICK HERE |
| Organic Reagents and Reagent Question-8 solution | Reagents BuLi with Nitroalkanes| Reaction Mechanism - Carruthers book for modern organic synthesis - Carbon-Carbon signal bond formation with reaction mechanism. |
CLICK HERE |
What is the best book for reagents and reaction chemistry?
We have to suggest the best book for reaction and reagents as a textbook Clayden is good for beginners and corresponds to advanced students. Clayden's book on Organic synthesis is clear on the concept of the reaction mechanism of basic knowledge under the organic chemistry success organolithium catalyzed, organometallic catalyzed, and any other nucleophile and basic reagents Which are commonly used in a regular organic reaction.
And another book for advanced-level students and research fellows following this book is Carruthers book for modern organic synthesis.
One of the most famous and popular books is A Guide to Mechanisms in organic synthesis by Peter Sykes. This book is good for any beginner-level student's purpose to learn and concept clearing under the reaction mechanism.
We have to suggest three reaction mechanisms with the reagents book for a beginner are
- Clayden's book for Organic synthesis
- Carruthers book for modern organic synthesis
- A Guide to Mechanisms in organic synthesis by Peter Sykes
Important Reagent List
| No. | Reagents | Full Name and Reagents |
|---|---|---|
| 1. | LiAH4 | Lithium Aluminium Hydride (Powerful reducing agent) |
| 2. | NaBH4 | Sodium borohydride (Reducing agent) |
| 3. | Zn(BH4)2 | Zinc Borohydride (Reducing agent) |
| 4. | DIBAL-H | Diisobutylaluminium hydride |
| 5. | NBS | N-BromoSuccinimide |
| 6. | H2O2 | Hydrogen peroxide |
| 7. | tBuOOH | tert-Butyl hydroperoxide |
| 8. | Sharpless Oxidation | tBuOOH, Ti(Oi-Pr)4, (+)DET or (-)DET [ Where Ti(Oi-Pr)4 is Titanium(IV) isopropoxide and DET is chiral diethyl tartrate. |
| 9 | RCO3H | Peroxy acid |
| 10. | Jacobsen epoxidation | Oxidizing reagent (Alkene to epoxide formation.) |
| 11. | OsO4 | Osmium tetroxide (It is an oxidizing reagent) |
| 12. | Lemieux Johnson Oxidation | OsO4 or RuO4 Catalyst, NaIO4 |
| 13. | KMnO4 | Potassium permanganate (Oxidizing agent) |
| 14. | MnO4 | Permanganate (Oxidizing agent) |
| 15. | Pb(OAc)4 | Lead Tetraacetate |
| 16. | Ag2CO3 | Silver carbonate |
| 17. | Oxidation by DMSO | Swern Oxidation: DMSO, (COCl)2 -60 degrees Celcius in the presence of NEt3 (Base) and absence of base. |
| 18. | PCC | Pyridinium Chlorochromate (an Oxidizing agent) |
| 19 | PDC | Pyridinium dichromate (an oxidizing agent) |
| 20 | SeO2 | Selenium dioxide (Is an oxidizing agent) |
| 21. | Ozonolysis | O3, Zn/ H2O |
| 22. | IBX and Dess Martin | 2-Iodoxybenzoic acid (IBX) |
| 23. | TEMPO | 2,2,6,6-Tetramethylpiperidinyloxy |
| 24. | Hydration | BH3, B2H6, Hg(OAc)2, NaBH4 |
| 25. | Hydrogenolysis | |
| 26. | R2CuLi | Gilman Reagent |
| 27. | RMgX | Grignard Reagent |
| 28. | Bu3SnH | Tributyltin Hydride |
| 29. | DDC | N, N′-Dicyclohexylcarbodiimide |
| 30. | DDQ | 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone |
| 31 | R-Li | Organolithium |
| 32. | LDA | Lithium Di-isopropyl Amide (LDA) |
